Was talking with a buddy while brewing last night (dortmunder) and forgot to add my salts (gypsum and cacl) to the sparge so I chucked them into the boil. I brew with RO. Any idea as to what the repercussions might be?
I thought the purpose of them was to adjust PH during the sparge. If you got the efficiency you wanted then you didn’t need them as I understand it. I don’t think they would do anything in the boil other than give you salty beer. But I could be wrong, have been before, probably will be again.
I batch sparge so I never bother adding the salts to my sparge water. I just add them to the kettle. I’d be more concerned about adding them if I fly sparged to make sure the ph didn’t rise too much over the 45-60 minutes of the sparge.
They will drop the pH in the mash, as the Ca combines with phytin from the malt to produce a H+ ion! which drops the mash pH. In RO water, no. Paul forgot to add to the sparge water, so the point was about that.
Good question; I suspect there’s no straightforward answer. Anecdotally, there must be some or people wouldn’t be able to adjust sparge pH using salts.
I don’t bother checking pH during the sparge anymore. It might make sense if you have hard water, but I never saw any significant deviation from the mash rest pH.