As for pH - you’d need some data to support your theory. Whichever method you use, there’s a risk of oversparging and raising pH too high, so it’s not so much the method that matters as the way an individual brewer does it.
Hot break is by definition the coagulated protein that forms in the boil. Decoction involves boiling so yes you can get hot break in a decoction. Not in a single infusion mash. You might get some denatured protein at 66C, but it isn’t called hot break.
No doubt, and it isn’t the technique that makes great beer. It is perfecting the one you use. I usually do large batches, fly sparging is better for me. Does it make me want to argue that it is a better technique than batch? Nodda, my MT is blue though.
That’s not completely true. Hot break are all proteins that denature and losing their quaternary or tertiary structures that had sufficient hydrophilic properties that made it soluble. It’s a general term for losing solubility due to loss of conformity as heat is applied. Cold break is a general term for the precipitation of proteins as solubility is lost as temperatures go down. Are you really suggesting that proteins only denature at 212F? Why is it then that glucanase denatures at lower temps than protease which denatures at lower temps than amylase?
I’ve seen this in nearly every batch of beer I’ve made, and I don’t batch sparge. I recirculate my mash with a pump during steps and mashout. If I’m trying for maximum fermentability and don’t mashout, then this layer does not form. At ~165F you start to see a light layer forming. At ~170F, you see a more pronounced layer, especially if you mashout longer than 10-15 minutes. From personal experience, I can tell you if you look away for a second and the mash hits 175-180F, then you will get a much thicker layer. You will see the same layer form when you do decoctions. You will also see this layer form if you apply to much heat as you are step mashing. I had the flame turned up too high once and hit ~5F per minute rise and this layer of break material formed during saccharification.
According to Palmer in a recent podcast on BrewStrong, flour grist is 100% gelatinized and in solution about 160-162F, so the flour argument has no legs, sorry. Besides, if it were flour, it should form on the top of a fly sparge grain bed during vorlauf as well.
In the original post, I did look for data by asking if he recorded the pH of each batch sparge…
Regardless, the nature of how buffers work don’t change based on brewing method. If you gradually add a liquid of different pH, the buffers will “buffer” the pH change until they are exhausted, at which time the pH begins to rise. Fly sparging allows buffers to do their job. If you dump all of the liquid out of your mash before sparging, then you have eliminated the buffer pool. Once you add the water back, you only have residual buffers from interstitial spaces and absorbed into the husks (maybe some adsorption too) to mitigate the pH change from the new sparge water (also why a lot of people sparge with RO). There is no chance for the buffers in the first mash to resist the change in pH, as they are now in the boil kettle.
In all of the hundreds (thousands?) of beers that I’ve judged, never once have I said something like “that one tastes like it’s fly sparged”.
And with all due respect to Marshall’s (and his team’s) work, please keep in mind that these are only single trials. That’s why Marshal encourages to try these for themselves. It’s also the reason Drew and I enlist lots of people to do the same experiment When it comes to “citizen science”, the more the better. If you want to get involved, go to www.experimenalbrew.com and sign up to be an IGOR. We’ll even provide some of the ingredients for experimenting.
You’re using the term hot break as though it’s synonymous with denatured protein, but that’s not correct. When you boil an egg the protein is completely denatured, but nobody calls it hot break. Hot break is a brewing term for the protein that coagulates in the first 10-20 minutes of the boil.
Some of it might well be denatured protein, you might be right about that.
Flour isn’t 100% soluble though. There’s more in it than just starch.
Whether you’re fly sparging or batch sparging, you’re diluting the wort in the mash and are going to overwhelm the buffering capacity either way. It would be interesting to know what happens to pH during batch 2 and batch 3 of a batch sparge. I reckon any buffering is lost on the 2nd batch, not so sure about the first. I batch sparge with a single batch, usually 20-25% of my total liquor. At that point there’s usually 3 litres of residual wort in the mash and maybe 4 litres of mash liquor added. I doubt pH rises significantly. Other people might see pH rise further if the volumes are different.
As I said, I think a lot depends on how it’s done. You can probably wreck any beer with either method or make perfect beer with either method. I don’t one is better than the other.
I’ve found that even when I batch sparge with distilled water, the pH will rise slightly.
Recently, I step mashed two lagers using hot water infusions and the step caused the pH to rise from 5.37 to 5.45 on the amber and 5.37 to 5.48 on the dunkel. On the dunkel, I also measured the pH during the sparge, and it was at 5.55.
I think those values are low enough that tannin extraction won’t be an issue, but I’ve only had a small taste of the amber, and the dunkel is still fermenting.
I used to mitigate this by adding a small dose of 10% phosphoric acid to the sparge water - something I might start doing again.