Measuring high gravity worts

I did a quick experiment to see what happened when both methods where used; i.e., one where equal volumes of water and a sugar solution are combined and measured, and the other where equal weights of water and a sugar solution are combined and measured. The refractometer measures in Brix, which is defined as % of sucrose by weight in a solution; where 1 gram of sucrose is in a 100 gram solution, you have 1 Brix. Note however that the actual measurement is made using light refraction, and the reading in brix is extrapolated from the result of that light refraction.

  1. a 10 brix solution was made by weighing 10 grams of table sugar on a scale that weighs to a tenth of a gram, and topping it off with water to make 100 grams total weight (Note: prior to the experiment, I made two solutions: one where 10 grams of sugar was combined with 100 grams of water – making 110 grams total weight, and the other where 10 grams of sugar had enough water added to make a 100 gram total weight solution; the 100 gram total weight solution gave the reading of 10.0, as expected)

  2. This sample gave a reading of 10.0 on my refractometer (a “zero” calibration was made to the refractometer just prior); as a cross check, I tested the sample with my hydrometer: 1.040

  3. 20 grams of sugar solution was combined with 20 grams of water; this gave a reading of 4.8 brix

  4. 15 mL of sugar solution was combined with 15 mL of water; this gave a reading of 5.0 brix

  5. I alternated the two samples, taking a total of four readings per sample; the results did not vary. I also carefully cleaned the refractometer between all readings

Now I grant that these results vary by a small amount, likely due to the sample solution being only 10 brix; perhaps a second run with a 20 or even 40 brix sample might better show any variance. But, the equal volumes method seemed to work best for diluting a sample to read half the actual brix of the solution.

I suspect that where refractometers are concerned, dilution of an equal amount of water does approximate the sugar content by half. I think this is because refractometers measure a refraction of light caused by the absolute volume of sucrose present, rather than its weight.
Also note: refractometers ONLY measure sucrose…higher gravity worts MAY read incorrectly, depending on the nature of the wort sugars that are present.

Just my $0.02 worth.