Just getting around to cleaning some corny kegs a friend gave me, and I have one with a brownish stain in the bottom that I can’t remove. It is probably a spot where a bit of liquid (assuming beer because he was a brewer but who knows) pooled for a long period of time. It’s not a solid brown spot. It’s more like sort of haphazard rings of various shades of brown and roughly 3" across.
So far I’ve tried PBW, Craft Meister Alkaline Brewery Wash, and StarSan with no luck.
I just want to use this keg for periodic cleaning of beer lines, so I’m not sure if the stain is a big deal. But I would feel better if I could get it cleaned up.
I guess it could be rust, but it sure doesn’t look like rust. I can’t imagine what else it could be though that wouldn’t have come off with the cleaners that I’ve tried.
Can I use phosphoric acid? And if yes, how much should I dilute it?
Here is advice from a metallurgist named Palmer. Bar Keepers Friend is the source of oxalic acid. You might need someone with skinny arms to reach the bottom to scrub. http://www.howtobrew.com/appendices/appendixB-1.html
Ha! I know exactly what you are talking about. Got my arm caught in one a few weeks back. Next time I will hold my wife upside down by her legs and let her go in for a good cleaning.
My arms are just long and skinny enough to get shoulder deep into a keg allowing me to rest my palm flat on the bottom. Makes my yearly deep clean and rebuild easier.
That is an almost sure way to cause rust. Muriatic acid (aka: hydrochloric acid) supplies the chloride ion that is what is needed to cause stainless steel to rust. Don’t ever use muriatic acid on stainless steel.
On a side note, organic stains and deposits can sometimes be dissolved with sodium hydroxide solution (lye). It is very aggressive with organic matter (including your skin), be careful with its use.
Martin,
I’m an engineer not a chemist, so I’ll gladly differ to your expertise. What would be a good, easily obtainable and reasonably safe acid to use to passivate SS?
I’m an engineer and not a chemist either. But, I understand the standard for SST passivation is Nitric acid. However as you are probably aware, its not really easily available to regular folks. As a semi-decent alternative, oxalic and citric acids are the active acids in BarKeepers Friend.