Weirdest thing: Sulfur Removal tip

I have a beer that I racked too early and it was just full of sulfur. Smelled absolutely fetid. I looked up some solutions and found a tip on a wine making forum that suggested pouring a small glass and stirring the wine with copper. And that if it works to try racking the wine through copper tubing.

Tried the stirring thing and side by side the difference is simply friggin’ amazing! The beer stirred with copper tastes and smells exactly as it should. The other smells a little like ass.

I’m blown away, had never heard of this technique. The beer stirred with copper is delicious and completely drinkable, the other I couldn’t finish an entire glass. Has anyone else heard of this?

Wow…alchemy!  Never heard of that.

Works with mead too. Sometimes just a “copper” penny in the secondary will fix the rotten farts, 'er Sulfur.  Cheers!!!

Good trick to know!  Got one for Acetaldehyde?

Leave it in the primary longer to avoid but It may go away as it conditions.  Cheers!!!

That’s why stills are made of copper.

My memory was jogged.  This is said to be what happens on the hot side, must happen on the cold side too.
Was it the rotten egg smell of H2S?

Copper ions react with the hydrogen sulfide produced during fermentation and reduce it to insoluble copper sulfide, which is left behind with the trub and yeast cake

From this, in the metals and liquids section.
http://www.byo.com/stories/projects-and-equipment/article/indices/20-build-it-yourself/1149-metallurgy-for-homebrewers

Yes, Jeff, that is essentially what the post said - that the copper reacts with the hydrogen sulfide. I’m just amazed at how well it works. It really is like magic.

Copper can be bad on the cold side as it can ppromote staling.  If the contact time is low, this may be good to get the H2S out. Not the first time I have seen a brewing rule go both ways.

Do you have any copper on the hot side in your system?  Might help reduce it, but the yeast may still produce more.

Used to, but now, no, not really. I am going to start adding a couple pieces to the boil now. I seem to have been having a problem with sulfur in beers lately, especially with dark beers. Hoping this will help eliminate the problem.

I wonder how much contact time you need.  Coul adding a piece of copper to the racking cane work.

Also, aren’t pennies made mostly of zinc now a days?

You can look it up to find the exact amount, but pennies are about 98% zinc.

For a 12 oz glass of beer it took about 3-5 seconds of stirring for the aroma and flavor to be completely gone. I’m going to just add a couple lengths of copper to the BT and let sit for an hour or so and sample it. Hopefully that will do the trick.

But, yeah, copper on the racking cane might very well be all that you would need.

Just thinking, when copper turns green that generally means its formed copper sulfate. I’d guess that the sulfer pulled out of the beer might be bonding to form copper sulfate. I’m pretty sure that stuff is toxic - I know it will kill fungus!

Interesting results Keith!

I think this Brewing Network episode with Jamil and Palmer sheds some more light on brewing with metals. It’s a good one. Check it out.

http://thebrewingnetwork.com/shows/Brew-Strong/Brew-Strong-09-29-08-Metals-that-Affect-Your-Beer

I remember reading somewhere that an all stainless steel brewery had to install a 6 inch section of copper piping in the transfer tubing in order to give the yeast enough trace copper for yeast health.  I don’t know if it also served the purpose of helping to drive off H2S.

Out of curiosity, wouldn’t pushing CO2 help drive off the H2S?

If so, one could create a copper diffusion disc and attach it to a length of silicone tubing attached to a CO2 tank… sanitize it and then just drop it in the BT (or corny keg, if you’re just a humble homebrewer) for a few minutes.

I had tried bubbling Co2 up from the bottom through a diffusion stone and it helped some but not enough. Perhaps I didn’t give it enough time but you can strip other aromas from the beer this way as well, not just sulphur. The copper trick works faster and better IMO.

Just don’t let it go too long, or it will pick up metallic off-flavors.  I’d keep a really close eye on it.

I have a 5" piece of 1/2" copper pipe in the hose between my kettle and the pump.  I read something somewhere about copper givin g some sort of yeast nutrient but as usual I can’t remember any details.  Old age sucks.

Yeah, I was always under the impression that due to low pH of beer that copper was only safe on the wort side, but Palmer says "Copper is relatively inert to both wort and beer. " from the link posted above. Still, I’m not going to take any chances. I’m aiming for short exposure.

Also, FWIW I think the mineral stripped for copper for yeast health is zinc, IIRC. There might be other trace elements as well.